Top 150+ Solved Pharmaceutical Organic Chemistry 3 MCQ Questions Answer

From 76 to 90 of 179

Q. What is the relation between the given compounds?

a. Diastereomers

b. constitutional isomers

c. enantiomers

d. identical

  • a. Diastereomers

Q. Which of the following statements regarding enantiomers not true?

a. All (+) enantiomers are levorotatory

b. All (-) enantiomers rotate plane polarized light in a clockwise direction

c. (+) and (-) enantiomers rotate plane polarized light in opposite directions

d. All R enantiomers are dextrorotatory

  • c. (+) and (-) enantiomers rotate plane polarized light in opposite directions

Q. Which of the following is/are the S-enantiomer of alanine?

a. Only 1

b. Only 2

c. 1 and 3

d. 2 and 3

  • c. 1 and 3

Q. Which of the following is capable of existing as a pair of enantiomers?

a. 2-methylpropane

b. 2-methylpentane

c. 3-methylpentane

d. 3-methylhexane

  • d. 3-methylhexane

Q. Which statement about a chiral compound A is incorrect?

a. A racemate contains equal amounts of (+)-A and (–)-A

b. If A is resolved, it is separated into its enantiomers

c. (+)-A can also be labelled R-A, because (+) means the same as R

d. (+)-A and (–)-A will rotate polarized light equally but in opposite directions

  • d. (+)-A and (–)-A will rotate polarized light equally but in opposite directions

Q. Which of the following is the definition of chirality?

a. The superimposability of an object on its mirror image

b. A molecule with a mirror image

c. The non-superimposability an object on its mirror image

d. A molecule that has a carbon atom with four different substituents

  • d. A molecule that has a carbon atom with four different substituents

Q. Which symmetry element makes the given compound achiral?

a. Plane of symmetry (POS)

b. Center of symmetry (COS)

c. Axis of symmetry (AOS)

d. Alternating axis of symmetry (AAOS)

  • a. Plane of symmetry (POS)

Q. Which of the following is the definition for enatiomerism?

a. A pair of stereoisomers each of which has two chirality centres

b. A pair of stereoisomers that are not mirror images of one another

c. A pair of stereoisomers that are non-superimposable mirror images of one another

d. Any pair of stereoisomers

  • c. A pair of stereoisomers that are non-superimposable mirror images of one another

Q. Which of the following notations is not used to distinguish between pairs of enantiomers?

a. R and S

b. E and Z

c. + and –

d. D and L

  • b. E and Z

Q. Which among the following is not true about enantiomerism?

a. Assignments of R and S labels and (+) and (–) labels are not connected

b. The labels R and S refer to different conformers

c. The labels (+) and (–) are used to distinguish enantiomers

d. The specific rotation of enantiomers is equal and opposite

  • b. The labels R and S refer to different conformers

Q. Which of the following molecules does not possess enantiomers?

a. CH3CH2CH2CHBrCH3

b. CH3CH2CBr2CH3

c. CH3CHBrCH2CH3

d. CHBr2CH2CHBrCH3

  • b. CH3CH2CBr2CH3

Q. What does a polarimeter measure?

a. Polarity of the substance

b. Angle of rotation of an optical active compound

c. Concentration of the substance

d. pH of the substance

  • b. Angle of rotation of an optical active compound

Q. . Polarimeter works on the principle of which of the following?

a. polarization of light

b. change of the electrical conductivity of solution with composition

c. change of angle of refraction with composition

d. change of electrical conductivity of solution with temperature

  • a. polarization of light
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